Carbon for engineering of a water-oxidizing catalyst.

Herein we report that the reaction of KMnO4 with cobalt nanoparticles coated with multiple graphene layers forms a promising catalyst toward water oxidation. The compound was characterized by scanning electron microscopy, energy-dispersive spectroscopy, high resolution transmission electron microscopy, X-ray diffraction, electronic spectroscopy, Fourier transform infrared spectroscopy, and atomic absorption spectroscopy. In addition to the Mn oxide-based characteristics of the catalyst, it is a conductive, self-healing, recycling, highly dispersible, magnetically separable, environmentally friendly, and nano-sized catalyst for water oxidation. The turnover frequency for the catalyst toward water oxidation is 0.1 and 0.05 (mmol O2 per mol Mn s) in the presence of cerium(iv) ammonium nitrate and photo-produced Ru(bpy)3(3+).